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Catalytic converter questions

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Old Mar 21st, 2006, 14:44   #1
gnhuk
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Default Catalytic converter questions

Can someone explain to me, in words of one syllable, how a catalytic converter works and is it possible to clean one out? I work in IT and have little knowledge of chemistry.

Having had my car running rich for months/years I seem to have cured it but..... I assume that the catalytic converter might be "sooted up" (bear with me I don't really understand how a cat works) and will therefore fail to work in the designed manner. However I'm now getting a sulpurous smell after about 10 miles so does this mean that the cat is cleaning itself or it's totally f*cked and needs replacing?

I've got a spare brand new cat (got lucky on ebay) so I can just sling it in the boot and tell the mechanic to replace if necessary (it's service/MOT time next week).
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Old Mar 21st, 2006, 15:23   #2
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Have you noticed that the "bad egg smell" is usually connected to brand new cars?
I would say it is cleaning itself.
Best to give it a long run to get it really hot and see what the emisions are!
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Old Mar 21st, 2006, 15:42   #3
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Smell can be either a failing cat or else the car is running too rich. You really need your emissions checking to sort out which is at fault.

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Old Mar 21st, 2006, 16:19   #4
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Two contradictory answers! I was under the impression that a cat, when it is thoroughly warmed up, might give a "bad egg smell" initially. This is not continuous but occurs when I get to the 10 mile(ish) mark in a journey. I've recently changed the coolant sensor for the ECU and the MPG has improved by about 15%. I plugged in the laptop afterwards and the O2 sensor 2 (I assume the rear one) now varies in value whereas before it never moved.

The car is going for a service & MOT on Monday and I don't expect to be able to give it a real thrash before then.
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Old Mar 22nd, 2006, 08:59   #5
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The second lambda monitors the emissions post cat - the fact that the lambda varies now says it is correct - readies should fluctuate failry rapidly between 0 and 1 volt. If before it didn't move it was probably stuck on 1 volt reading i.e. rich hance smell from cat.

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Old Mar 22nd, 2006, 09:53   #6
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Thanks Mike, I think I'm beginning to understand the process. The second sensor wasn't moving before I changed the ECU temp sender (it was reading a solid number without fluctuation) but now varies. The bit that IS confusing me is that before I changed the sender there wasn't a smell from the cat but now, post change, after I've done about 10 miles there is a brief "odour" which goes away again. Maybe the cat does that once it's warmed up to operating temp as it finally burns off the sh1*?

I'll still put the spare cat in the boot when I take it in on Monday, just in case, as I don't want to be paying full whack for a replacement. I presume the Lamda sensors are probably okay...............?
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Old Mar 22nd, 2006, 11:18   #7
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without getting too technical, a catalytic converter basically converts Carbon Monoxide into Carbon Dioxide, Nitrogen Oxide into Nitrogen and Water, and Hydrocarbons into Carbon Dioxide and Water the reason for this is that
Carbon Monoxide is poisionous, Nitrogen Oxide causes Acid rain and unburnt Hydrocarbons produce Smog i hope this has helped.
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Old Mar 22nd, 2006, 13:14   #8
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Whoosh (sound of the above explanation flying over my head!)


That is far too complicated for me...........
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Old Mar 22nd, 2006, 18:39   #9
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the simpler version goes..............dirty in and clean out,
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